Air pollution- Particulate emission by industries and automobiles –smog-acid rain-Ozone hole

Air pollution is the introduction of chemicals, particulate matter, or biological materials that cause harm or discomfort to humans or other living organisms, or cause damage to the natural environment or built environment, into the atmosphere.

Sources

·         "Stationary Sources" include smoke stacks of power plants, manufacturing facilities (factories) and waste incinerators, as well as furnaces and other types of fuel-burning heating devices, chemicals, dust and controlled burn practices in agriculture and forestry management. "Mobile Sources" include motor vehicles, marine vessels, aircraft and the effect of sound, Military, such as nuclear weapons, toxic gases, germ warfare and rocketry etc.

Particulates pollution

Particulates – also known as particulate matter (PM), fine particles, and soot – are tiny subdivisions of solid matter suspended in a gas or liquid. In contrast, aerosol refers to particles and/or liquid droplets and the gas together. A particle with an aerodynamic diameter of 10 micrometers moves in a gas like a sphere of unit density (1 gram per cubic centimeter) with a diameter of 10 micrometers. PM diameters range from less than 10 nanometers to more than 10 micrometers.

The notation PM₁₀ is used to describe particles of 10 micrometers or less and PM_2.5 represents particles less than 2.5 micrometers in aerodynamic diameter.

Secondary particles derive from the oxidation of primary gases such as sulfur and nitrogen oxides into sulfuric acid (liquid) and nitric acid (gaseous). The precursors for these aerosols—i.e. the gases from which they originate—may have an anthropogenic origin (from fossil fuel or coal combustion) and a natural biogenic origin. In the presence of ammonia, secondary aerosols often take the form of ammonium salts; i.e. ammonium sulfate and ammonium nitrate (both can be dry or in aqueous solution); in the absence of ammonia, secondary compounds take an acidic form as sulfuric acid (liquid aerosol droplets) and nitric acid (atmospheric gas). Secondary sulfate and nitrate aerosols are strong light-scatterers. This is mainly because the presence of sulfate and nitrate causes the aerosols to increase to a size that scatters light effectively.

Organic matter (OM) can be either primary or secondary, the latter part deriving from the oxidation of VOCs; organic material in the atmosphere may either be biogenic or anthropogenic. Organic matter influences the atmospheric radiation field by both scattering and absorption. Another important aerosol type is constitute of elemental carbon (EC, also known as black carbon, BC): this aerosol type includes strongly light-absorbing material and is thought to yield large positive radiative forcing. Organic matter and elemental carbon together constitute the carbonaceous fraction of aerosols.

The composition of particulate matter that generally causes visual effects such as smog consists of sulphur dioxide, nitrogen oxides, carbon monoxide, mineral dust, organic matter, and elemental carbon also known as black carbon or soot. The particles are hydroscopic due to the presence of sulphur, and SO₂ is converted to sulphate when high humidity and low temperatures are present. This causes the reduced visibility and yellow color

Acid rain

Acid rain is a rain or any other form of precipitation that is unusually acidic, meaning that it possesses elevated levels of hydrogen ions (low pH). It can have harmful effects on plants, aquatic animals, and infrastructure. Acid rain is caused by emissions of carbon dioxide, sulfur dioxide and nitrogen oxides which react with the water molecules in the atmosphere to produce acids.

The principal cause of acid rain is sulfur and nitrogen compounds from human sources, such as electricity generation, factories, and motor vehicles. Coal power plants are one of the most polluting. The gases can be carried hundreds of kilometers in the atmosphere before they are converted to acids and deposited. In the past, factories had short funnels to let out smoke but this caused many problems locally; thus, factories now have taller smoke funnels. However, dispersal from these taller stacks causes pollutants to be carried farther, causing widespread ecological damage

Adverse effects

Acid rain has been shown to have adverse impacts on forests, freshwaters and soils, killing insect and aquatic life-forms as well as causing damage to buildings and having impacts on human health.

Surface waters and aquatic animals

Both the lower pH and higher aluminium concentrations in surface water that occur as a result of acid rain can cause damage to fish and other aquatic animals. At pHs lower than 5 most fish eggs will not hatch and lower pHs can kill adult fish. As lakes and rivers become more acidic biodiversity is reduced. Acid rain has eliminated insect life and some fish species, including the brook trout in some lakes, streams, and creeks in geographically sensitive areas, such as the Adirondack Mountains of the United States. However, the extent to which acid rain contributes directly or indirectly via runoff from the catchment to lake and river acidity (i.e., depending on characteristics of the surrounding watershed) is variable. The United States Environmental Protection Agency's (EPA) website states: "Of the lakes and streams surveyed, acid rain caused acidity in 75 percent of the acidic lakes and about 50 percent of the acidic streams".

Soils

Soil biology and chemistry can be seriously damaged by acid rain. Some microbes are unable to tolerate changes to low pHs and are killed. The enzymes of these microbes are denatured (changed in shape so they no longer function) by the acid. The hydronium ions of acid rain also mobilize toxins such as aluminium, and leach away essential nutrients and minerals such as magnesium.

Soil chemistry can be dramatically changed when base cations, such as calcium and magnesium, are leached by acid rain thereby affecting sensitive species, such as sugar maple (Acer saccharum).

Human health effects

Acid rain does not directly affect human health. The acid in the rainwater is too dilute to have direct adverse effects. However, the particulates responsible for acid rain (sulfur dioxide and nitrogen oxides) do have an adverse effect. Increased amounts of fine particulate matter in the air do contribute to heart and lung problems including asthma and bronchitis.

Acid rain can also damage buildings and historic monuments, especially those made of rocks such as limestone and marble containing large amounts of calcium carbonate. Acids in the rain react with the calcium compounds in the stones to create gypsum, which then flakes off.

The effects of this are commonly seen on old gravestones, where acid rain can cause the inscriptions to become completely illegible. Acid rain also increases the corrosion rate of metals, in particular iron, steel, copper and bronze.

Ozone layer

The ozone layer is a layer in Earth's atmosphere which contains relatively high concentrations of ozone (O₃). This layer absorbs 97–99% of the Sun's high frequency ultraviolet light, which is potentially damaging to the life forms on Earth. It is mainly located in the lower portion of the stratosphere from approximately 30 to 40 kilometres (19 to 25 mi) above Earth, though the thickness varies seasonally and geographically. The "Dobson unit", a convenient measure of the columnar density of ozone overhead

Ozone in the Earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O₂), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O₂ to create ozone, O₃. The ozone molecule is also unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O₂ and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle, thus creating an ozone layer in the stratosphere, the region from about 10 to 50 kilometres (33,000 to 160,000 ft) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 20 and 40 kilometres (12 and 25 mi), where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only 3 millimeters thick.

Ozone depletion

The ozone layer can be depleted by free radical catalysts, including nitric oxide (NO), nitrous oxide (N₂O), hydroxyl (OH), atomic chlorine (Cl), and atomic bromine (Br). While there are natural sources for all of these species, the concentrations of chlorine and bromine have increased markedly in recent years due to the release of large quantities of man-made organohalogen compounds, especially chlorofluorocarbons (CFCs) and bromofluorocarbons. These highly stable compounds are capable of surviving the rise to the stratosphere, where Cl and Br radicals are liberated by the action of ultraviolet light. Each radical is then free to initiate and catalyze a chain reaction capable of breaking down over 100,000 ozone molecules. The breakdown of ozone in the stratosphere results in the ozone molecules being unable to absorb ultraviolet radiation. Consequently, unabsorbed and dangerous ultraviolet-B radiation is able to reach the Earth’s surface. Ozone levels over the northern hemisphere have been dropping by 4% per decade. Over approximately 5% of the Earth's surface, around the north and south poles, much larger seasonal declines have been seen, and are described as ozone holes.